省沽油中硒含量及其测定方法研究

采用消化液硝酸／高氯酸消解法、硝酸-硫酸消解法和微波消解方法消化省沽油，用原子吸收分光光度法测定硒（Se）含量。比较了3种消解方法在测定省沽油中的硒含量。发现微波消解法测定野生省沽油（干菜）中Se含量准确性好、时间段效率高、对环境污染少、操作简单。     

微波消解-流动注射分光光度法测定总氮和总磷

以碱性过硫酸钾溶液为消解液,采用微波消解-流动注射分光光度法测定水中总氮和总磷。在碱性过硫酸钾溶液中氢氧化钠质量浓度为9.6g/L、微波功率为320W、消解管长度为16m的条件下,总氮和总磷的检出限分别为0.040m g/L和0.020mg/L,线性范围分别为0.040～3.500mg/L和0.020～2.500mg/L,相对标准偏差分别为1.6%和1.0%。微波消解-流动注射分光光度法应用于河水、湖水、化工废水等实际水样中总氮和总磷的测定,加标回收率分别为95.7%～98.1%和97.2%～102.2%。     

流动注射分光光度法测定水中铝的含量

以桑色素作显色剂，采用流动注射分光光度法测定水中铝的含量。在桑色素质量浓度为0．8g／L、聚氧乙烯辛基苯基醚体积分数为1．0％、进样环体积为400μL、检测波长420nm的条件下，采用流动注射分光光度法对水中铝的含量进行测定，本方法的线性范围为2～300μg／L，检出限（信噪比为3）为0．124μg／L，相对标准偏差为2．9％，加标回收率为96．4％～101．8％。     

多波长分光光度法在环境监测中的应用

根据NO2^-与AY(吖啶黄)的重氮化偶联反应。研究了反应的最佳条件，利用四波长处吸光度加和值与NO2^-浓度在一定范围内呈线性关系。建立四波长测定微量NO2^-含量的新方法。应用于环境样品的监测。获得了满意的效果。符合环境监测的要求。     

光度法标定标准溶液方法探讨

提出用分光光度法标定标准溶液的概念和方法，并对其可行性进行了研究和探讨。     

水和废水中黄磷的测定

试验了黄磷在紫外光区的吸收光谱,建立了紫外分光光度法测定水和废水中黄磷的方法.该方法不需酸化、氧化,可在萃取后直接比色测定.当样品中含有石油类干扰物质时,可用含氧化剂的酸性水溶液对萃取液进行反萃取即能将其排除.该方法灵敏,具有测定范围宽、准确度高、精密度好、操作简便等特点.     

Development of a highly sensitive extractive spectrophotometric method for the determination of nickel(II) from environmental matrices using N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone

Nickel(II) reacts with N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone (ECCT) and forms a yellow colored complex, which was extracted into n-butanol from sodium acetate and acetic acid buffer at pH 6.0. The absorbance value of the Ni(II)-ECCT complex was measured at different intervals of time at 400nm, to ascertain the time stability of the complex. The extraction of the complex into the solvent was instantaneous and stable for more than 72h. The system obeyed Beer's law in the concentration range of 1.2-5.6mugml(-1) of nickel(II), with an excellent linearity and a correlation coefficient of 0.999. The molar absorptivity and Sandell's sensitivity of the extracted species were found to be 1.114x10(4)Lmol(-1)cm(-1) and 5.29x10(-3)mugcm(-2) at 400nm, respectively. Hence, a detailed study of the extraction of nickel(II) with ECCT has been undertaken with a view to developing a rapid and sensitive extractive spectrophotometric method for the determination of nickel(II) when present alone or in the presence of diverse ions which are usually associated with nickel(II) in environmental matrices like soil and industrial effluents. Various standard alloy samples (CM 247 LC, IN 718, BCS 233, 266, 253 and 251) have been tested for the determination of nickel for the purpose of validation of the present method. The results of the proposed method are comparable with those from atomic absorption spectrometry and were found to be in good agreement.     

荧光光谱法在环境监测中的应用

简要综述了荧光光谱在环境监测中近几年的应用。内容包括方法原理、方法的建立，有关荧光体系的研究，以及与其他技术的联用等一些最新进展。指出：荧光光谱法具有灵敏度高、选择性强、试样量少和测定简单等优点，为复杂环境样品中微量元素及痕量物质的分析提价了新手段，与其他手段结合使用，环境分析将具有更加广阔的前景，     

紫外分光光度法在水中阴离子表面活性剂标准样品研制中的应用

研究了阴离子表面活性剂水溶液的紫外吸收特性，并将研究结果用于阴离子表面活性剂水质标样的稳定性，均匀性和定值工作，简化了操作手续，获得了准确的分析结果。     

间接光度法测定水中硫酸根

介绍了用一定过量的氯化钡沉淀SO2-4,余下的Ba2+与加入一定过量的铬酸钾反应,存在于溶液中的铬酸根在pH3.4的HAc-NaAc介质中与联邻甲苯胺生成蓝绿色的产物,并且溶液的颜色随硫酸根的量呈线性关系,借此进行光度法测定硫酸根.本法选620nm为测定波长,硫酸根含量在0～125μg/10ml范围符合比尔定律.方法在用于测定自来水中硫酸根时,结果满意.